Concepts
36 concepts
biogeochemical reactions
weathering
reactive transport
nitrate removal
Removal of nitrate from porewater through denitrification and other biogeochemical processes
redox reactions
aerobic respiration
pyrite oxidation
Oxidative dissolution of pyrite mineral producing sulfuric acid and iron oxides under oxic conditions
isotopic fractionation
iron redox cycling
anaerobic methane oxidation
Microbial process where methane is oxidized under anoxic conditions, often coupled to reduction of alternative electron acceptors
nitrification
The oxidation of ammonia to nitrate via nitrite, linking nitrogenous organic matter remineralization to nitrogen loss processes in the microbial N-cycle
shale weathering
Chemical and physical breakdown of sedimentary shale rocks through interactions with water, atmospheric gases, and biological processes
DIC export
acid-base interactions
end-member mixing
redox zonation
Spatial organization of aerobic and anaerobic zones based on dissolved oxygen availability that controls biogeochemical reactions
Iron oxidation
sulfate reduction
Microbial reduction of sulfate coupled to organic matter oxidation in anoxic environments resulting in formation of low solubility sulfide minerals
metal mobilisation
sorption
Fe(II)-NOM complexation
Formation of coordination complexes between Fe(II) ions and natural organic matter ligands
decomposition rates
mineral dissolution kinetics
Rate laws governing the chemical breakdown of primary minerals as functions of temperature, pH, and saturation state
metal-oxide precipitation
natural attenuation
oxygen ingress
photoreductive dissolution
calcium uranium carbonate complexes
carbon evasion
The transfer of CO2 from water to atmosphere through gas exchange at the air-water interface
carbon partitioning
Distribution of carbon between different reservoirs including atmosphere, subsurface, and exported dissolved phases during weathering processes
chemolithoautotrophic DNRA
chlorite dissolution
organic carbon depolymerization
porosity evolution
Changes in rock porosity and permeability due to mineral dissolution and precipitation reactions during weathering
